Charge transfer adducts of rare earth 3,5-dinitrobenzoates with N,N,N′,N′-tetramethyl-p-phenylenediamine
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- 作者：Pavel S. Koroteev ; pskoroteev@list.ru" class="auth_mail" title="E-mail the corresponding author ; Andrey B. Ilyukhin ; Nikolay N. Efimov ; Elena A. Ugolkova ; Zhanna V. Dobrokhotova ; Vadim V. Minin ; Vladimir M. Novotortsev
- 关键词：Charge transfer complex ; Lanthanide carboxylate ; Supramolecular structure ; EPR study ; Magnetic study ; Spectral study
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：442
- 期：Complete
- 页码：86-96
- 全文大小：1616 K
文摘
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Rare earth dinitrobenzoates form adducts with N,N,N′,N′-tetramethylphenylenediamine.
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Charge transfer determines supramolecular structures of the adducts.
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Charge transfer results in significant paramagnetism of Y compounds.
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Ln dinitrobenzoate polymers are formed in absence of tetramethylphenylenediamine.
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Dysprosium complex manifests single molecule magnet properties.