Synthesis and X-ray crystal structure of the dirhenium complex Re2(i-C3H7COO)4Cl2 and its interactions with the DNA purine nucleobases
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- 作者：Alexander V. Shtemenkoa ; shtemenko@ukr.net" class="auth_mail" title="E-mail the corresponding author ; Helen T. Chifotidesb ; Dina E. Yegorovaa ; Natalia I. Shtemenkoc ; Kim R. Dunbarb
- 关键词：Dirhenium ; DNA purine nucleobases ; Anticancer ; NMR ; Quadruple bond ; Electronic spectroscopy
- 刊名：Journal of Inorganic Biochemistry
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：153
- 期：Complete
- 页码：114-120
- 全文大小：697 K
文摘
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Cis-Re2(i-C3H7COO)4Cl2 (I) was synthesized and characterized by X-ray crystallography.
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Purine nucleobases form with I bis-adducts of the type cis-Re2(i-C3H7CO2)2(nucleobase)2Cl2.
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Substituted 9R-guanine and 9R-adenine bridge I at equatorial sites via N7/O6 and N1/N6, respectively.