Solid- and gas-phase structures and spectroscopic and chemical properties of tris(pentafluorosulfanyl)amine, N(SF₅)₃, and bis(pentafluorosufanyl)aminyl radical, N(SF₅)₂

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• 作者：Jon B. Nielsen^a ; Petra Zylka^b ; Marc Kronberg^c ; Xiaoqing Zeng^d ; ^{xqzeng@suda.edu.cn} ; Kerry D. Robinson^a ; Simon G. Bott^a ; Hongming Zhang^a ; Jerry L. Atwood^a ; Heinz Oberhammer^b ; ^{heinz.oberhammer@uni-tuebingen.de} ; Helge Willner^e ; ^{willner@uni-wuppertal.de} ; Joseph S. Thrasher^a ; ^f ; ^{thrash5@clemson.edu} ; ^{fluorine@bama.ua.edu}
• 关键词：Gas electron diffraction ; Single crystal X-ray diffraction ; Stability ; Vibrational spectroscopy ; Quantum chemical calculations
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：15 March 2017
• 年：2017
• 卷：1132
• 期：Complete
• 页码：11-19
• 全文大小：964 K
• 卷排序：1132

文摘

Mechanism of formation and thermal decay of N(SF5)3 and N(SF5)2. Gas electron diffraction of N(SF5)3 and N(SF5)2. Single crystal X-ray diffraction of N(SF5)3. Vibrational and UV–vis spectra of N(SF5)3 and N(SF5)2. Quantum chemical calculations of N(SF5)3 and N(SF5)2.