Synthesis, crystal structures and characterization of two novel organic-inorganic hybrid compounds (C₅NH₆)₆Bi₄Br₁₈ and [C(NH₂)₃]₃BiI₆

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• 作者：S.G. Li ; ^{shigengli861224@126.com} ; L. Chen ; Y. Xiang
• 关键词：Organic-inorganic hybrids ; X-ray diffraction ; Crystal structure ; DSC ; Dielectric
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：1130
• 期：Complete
• 页码：617-622
• 全文大小：1232 K
• 卷排序：1130

文摘

Tow novel hybrid compounds, (C5NH6)6Bi4Br18 and [C(NH2)3]3BiI6 were synthesized at room temperature by slow evaporation. The crystal packing is ensured by hydrogen bonds. The phase transition of (C5NH6)6Bi4Br18 and [C(NH2)3]3BiI6 were studied using the DSC experiments. These materials were also investigated by elemental analysis and XRPD.