Biphenyl-cis-diol chemistry to access enantiopure aryl-substituted organoiron complexes

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• 作者：G. Richard Stephenson^a ; ^{g.r.stephenson@uea.ac.uk"" rel=""nofollow} ; Christopher E. Anson^b ; Graham J. Swinson^a
• 关键词：Organoiron ; Biotransformation ; Pseudomonas putida ; Stereoselective complexation ; Circular dichroism
• 刊名：Tetrahedron Letters
• 出版年：2011
• 出版时间：13 July 2011
• 年：2011
• 卷：52
• 期：28
• 页码：3547-3550
• 全文大小：395 K

文摘

The endo face selectivity of the complexation of the biologically derived 3-phenyl-1,2-dihydroxycyclohexa-3,5-diene ligand has been proved by an X-ray crystallographic study of the enantiopure (1R,2S,3S) η⁴ tricarbonyliron complex, and the correlation between the absolute configuration of the complex and its circular dichroism curve has been established to provide a basis on which to assign absolute configurations in the synthetically important [‘–(Ar)CCH–CHCH–’]Fe(CO)₃ series.