Organo-iron mediated synthesis of functional dendrimers with 1 → 3 connectivity

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• 作者：Didier Astruc ; ^a ; ^{d.astruc@ism.u-bordeaux1.fr"" rel=""nofollow} ; Jaime Ruiz^a
• 关键词：Organoiron ; Arene ; Sandwich complex ; Dendrimer ; Olefin
• 刊名：Journal of Organometallic Chemistry
• 出版年：2011
• 出版时间：15 August 2011
• 年：2011
• 卷：696
• 期：17
• 页码：2864-2869
• 全文大小：557 K

文摘

The organo-iron mediated activation of arene in the sandwich complexes [FeCp(η⁶-arene)][PF₆] is shown to produce 1 → 3 connectivity at benzylic positions that was utilized for dendrimer syntheses. This mini-review of the work carried out in the authors’ laboratory summarizes this principle and its applications with emphasis on recent significant improvements in the CpFe⁺-mediated reactions, recyclability of the CpFe⁺ group, mechanistic features and examples of efficient and useful functionalization reactions.