Piano-stool benzothiazol-2-ylidene Ru(II) complexes for effective transfer hydrogenation of carbonyls
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- 作者：Zeynep İpek Oruç ; a ; Lü ; tfiye Gö ; ka ; Hayati Tü ; rkmena ; hayatiturkmen@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; Onur Şahinb ; Orhan Bü ; yü ; kgü ; ngö ; rc ; Bekir Ç ; etinkayaa
- 关键词：Benzothiazolium salts ; NSHC-Ru(II) complexes ; The transfer hydrogenation ; Catalysis
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 April 2016
- 年：2016
- 卷：807
- 期：Complete
- 页码：36-44
- 全文大小：1075 K
文摘
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A series benzothiazolium bromides with a variety of alkyl chain or benzyl substituents on N atom were synthesized and metalated with ruthenium precursors.
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The catalytic properties of the complexes in transfer hydrogenation reaction of ketones and aldehydes were investigated.
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Their catalytic properties may be interpreted that electronic influences and micele effects of the ligand.