Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) species
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- 作者：Orlando Santoroa ; Fady Nahrab ; David B. Cordesa ; Alexandra M.Z. Slawina ; Steven P. Nolanb ; c ; Catherine S.J. Cazina ; ccazin@gmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：N-Heterocyclic carbenes ; Zinc ; Methylation ; CO2
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：423
- 期：Complete
- 页码：85-91
- 全文大小：1811 K
文摘
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A library of stable [(NHC)H][ZnXY2] species was synthesized.
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The structure of the salts was unambiguously assessed by X-ray diffraction analyses.
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The catalytic activity of the novel species was tested in the methylation of amines with CO2 as carbon feedstock.