Nonlinear viscoelastic properties of industrial relevant guar gum derivatives by large amplitude oscillatory shear flow.

Nonlinear stress waveforms were analyzed by FT-rheology and orthogonal stress decomposition along the MITlaos framework.

Rheological fingerprint in the Pipkin space to visualize breakup of aggregates as function of deformation and time scale.

Characteristic relaxation time of superstructures in aqueous guar gum derivative solutions is proposed.