New copper porphyrins as functional models of catechol oxidase

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• 作者：Kelly A.D.F. Castro^a ; ^b ; ¹ ; Joã ; o M.M. Rodrigues^b ; ¹ ; Ricardo F. Mendes^c ; Maria da Graç ; a P.M.S. Neves^b ; ^gneves@ua.pt ; Má ; rio M.Q. Sim&otilde ; es^b ; José ; A.S. Cavaleiro^b ; Filipe A. Almeida Paz^c ; Joã ; o P.C. Tomé ; ^b ; ^d ; ^jtome@ua.pt ; Shirley Nakagaki^a ; ^{shirleyn@ufpr.br}
• 关键词：Porphyrin ; Copper ; Catechol oxidation ; Catechol oxidase ; Hydrogen peroxide ; Heterogeneous catalysis
• 刊名：Journal of Catalysis
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：344
• 期：Complete
• 页码：303-312
• 全文大小：1155 K
• 卷排序：344

文摘

Synthesis and characterization of new copper porphyrins and coordination polymer. Catechol oxidation in the presence of air or hydrogen peroxide. Catalysts’ performance depends on the porphyrin structure. Cu(II) porphyrin is studied by single-crystal X-ray diffraction. The recyclability capability of heterogeneous catalyst was investigated.