Synthesis and structure of nickel and copper complexes containing the N-allyl-o-hydroxyacetophenoniminato ligand and the application of copper complex as catalyst for aerobic alcohol oxidations

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• 作者：Marí ; a del Mar Conejo^a ; Paloma Á ; vila^a ; Eleuterio Á ; lvarez^b ; Agustí ; n Galindo^a ; ^{galindo@us.es}
• 关键词：Copper ; Nickel ; Oxidation ; Catalysis ; Ionic liquids ; DFT
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：638-644
• 全文大小：1093 K
• 卷排序：455

文摘

The novel compound HLallyl was prepared by a solvent-free synthetic procedure. The first structurally characterised complexes with the Lallyl ligand are reported. Cu-complex is a good catalyst for the aerobic oxidation of benzylic-type alcohols. The use of ionic liquids as solvents allowed the catalyst recycling.