Glycerol electro-oxidation on bismuth-modified platinum single crystals

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• 作者：Amanda C. Garcia^a ; ^b ; Yuvraj Y. Birdja^a ; Germano Tremiliosi-Filho^b ; Marc T.M. Koper^a ; ^{m.koper@lic.leidenuniv.nl}
• 关键词：Glycerol oxidation ; Electrocatalysis ; Platinum ; Bismuth ; Selectivity promoter
• 刊名：Journal of Catalysis
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：346
• 期：Complete
• 页码：117-124
• 全文大小：1069 K
• 卷排序：346

文摘

Bismuth on Pt(1 1 1) electrode improves the activity of the related reaction. Bi on Pt(1 1 1) surface increases the selectivity of the reaction to DHA. Interaction of the Bi adatom with the enediol intermediate increases the selectivity to DHA.