Highly active and durable methanol electro-oxidation catalyzed by small palladium nanoparticles inside sulfur-doped carbon microsphere

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• 作者：Xiangheng Niu^a ; ^b ; Qingang Xiong^c ; ^{qgxiong@126.com} ; Jianming Pan^a ; ^b ; ^{pjm@ujs.edu.cn} ; Xin Li^b ; Wenchi Zhang^b ; Fengxian Qiu^b ; Yongsheng Yan^a
• 关键词：Small palladium nanoparticle ; Doped carbon microsphere ; MOR ; Electro-catalytic activity ; Operation durability
• 刊名：Fuel
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：190
• 期：Complete
• 页码：174-181
• 全文大小：1869 K
• 卷排序：190

文摘

Small Pd NPs inside S-doped CMS was synthesized. r-GSH was used as the reductant and capping agent as well as the C and S sources. The synthesized catalyst demonstrates high electro-catalytic activity toward MOR. The synthesized catalyst shows excellent stability of electro-catalytic activity.