Selective oxidation of olefins with aqueous hydrogen peroxide over phosphomolybdic acid functionalized knitting aryl network polymer
详细信息 查看全文
- 作者：Xiaojing Songa ; Wanchun Zhua ; Yan Yanb ; Hongcheng Gaoa ; Wenxiu Gaoa ; Wenxiang Zhanga ; Mingjun Jiaa ; jiamj@jlu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Phosphomolybdic acid ; Knitting aryl network polymer ; Immobilization ; Selective oxidation ; Olefins
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：413
- 期：Complete
- 页码：32-39
- 全文大小：1759 K
文摘
- •
PMA/KAP was obtained by supporting phosphomolybdic acid on PPh3 functionalized KAP.
- •
PMA/KAP is active and stable catalyst for olefin oxidation with H2O2/ethyl acetate.
- •
Multi-weak interaction exits between PMA unit and PPh3 ligands knitted in the KAP.
- •
Degradation of PMA to small species can be inhibited by the multi-weak interaction.