A convenient preparation of La₂CuO₄ from molecular precursors

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• 作者：Daniela Belli Dell'Amico^a ; Alessio Di Giacomo^a ; Lorenzo Falchi^a ; Luca Labella^a ; ^{luca.labella@unipi.it} ; Marcello Marelli^b ; Claudio Evangelisti^b ; Marco Lezzerini^c ; Fabio Marchetti^a ; Simona Samaritani^a
• 关键词：Molecular precursors ; Mixed metal oxides ; Dialkylcarbamato complexes ; Lanthanum cuprate ; Hydrolysis
• 刊名：Polyhedron
• 出版年：2017
• 出版时间：17 February 2017
• 年：2017
• 卷：123
• 期：Complete
• 页码：33-38
• 全文大小：1044 K
• 卷排序：123

文摘

Exhaustive hydrolysis of a mixture of [La4(CO3)(O2CNBu2)10] and [Cu(O2CNBu2)(py∗)2] (py∗ = 4-dimethylamino pyridine) in molar ratio 1/2 corresponding to a La/Cu molar ratio 2/1 was carried out in toluene at room temperature. The carbamato derivatives of lanthanum and copper can be easily prepared by extraction of the metal ions from aqueous solution into heptane by the NHBu2/CO2 system, according to a method previously reported. The copper precursor was selected amongst a number of derivatives in respect of its easy tractability. The tetragonal modification T′ of La2CuO4 was obtained by treatment at 600 °C of the intermediate mixed carbonate. The thermal treatment of T′-La2CuO4 at 850 °C, followed by cooling down to room temperature, afforded the orthorhombic modification of the mixed oxide.