One 2D Ni(II)-based compound showing diamagnetic-paramagnetic transition

详细信息    查看全文

• 作者：Wen-yuan Xu ; Xiao-zhao Tian ; Gong-ming Sun ; Yu-mei Song ; Zi-zun Yuan ; Zhen-wei Liao ; Hai-xiao Huang ; Ming-biao Luo ; Shu-juan Liu ; Feng Luo ; ^{ecitluofeng@163.com}
• 关键词：Ni(II) compound ; OPDA ; Inorganic NiCl2 net ; Diamagnetic-paramagnetic transition
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 出版时间：March, 2012
• 年：2012
• 卷：17
• 期：Complete
• 页码：68-70
• 全文大小：627 K

文摘

The title complex, [Ni(OPDA)Cl₂]_n (1, OPDA = o-Phenylenediamine), is synthesized hydrothermally. The single crystal X-ray diffraction reveals that compound 1 is a 2D honeycomb net, where the Ni(II) ions are bridged by both single and double Cl^- bridges. Magnetic studies of it disclose an interesting diamagnetic-paramagnetic transition.