The factors that influence solubility in perfluoroalkane solvents
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- 作者：Michael H. Abrahama ; m.h.abraham@ucl.ac.uk" class="auth_mail" title="E-mail the corresponding author ; William E. Acreeb ; Enrico Matteolic
- 关键词：Perfluoroalkanes ; Hydrophobic effects ; Solubility ; Partition coefficients ; Abraham descriptors ; Linear free energy relationship ; Principal component analysis ; Scaled particle theory
- 刊名：Fluid Phase Equilibria
- 出版年：2016
- 出版时间：15 August 2016
- 年：2016
- 卷：421
- 期：Complete
- 页码：59-66
- 全文大小：378 K
文摘
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Data on solvation of solutes in perfluoroalkane solvents collected.
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Gas-perfluoroalkane partition coefficients, K, analysed.
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The main influence on log K is a solute size effect.
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The size effect is a combination of cavity and interaction effects.
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Cavity effects calculated by Scaled Particle Theory.