Solvent effect on the allylic oxidation of cyclohexene catalyzed by nitrogen doped carbon nanotubes
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- 作者：Yonghai Cao ; Hao Yu ; yuhao@scut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Hongjuan Wang ; Feng Peng ; cefpeng@scut.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Selective oxidation ; Cyclohexene ; Solvent effect ; Carbon nanotubes ; 2-cyclohexen-1-one ; Nitrogen doping
- 刊名：Catalysis Communications
- 出版年：2017
- 出版时间：5 January 2017
- 年：2017
- 卷：88
- 期：Complete
- 页码：99-103
- 全文大小：811 K
文摘
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Solvents affect the oxidation of cyclohexene catalyzed by N-doped CNTs.
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The higher polarity is beneficial for the activity in aliphatic solvents.
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Aromatic solvents are less reactive due to the competitive adsorption.
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A modest solvent basicity is required for high reactivity.
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2-cyclohexen-1-one selectivity slightly increases with solvent polarity.