Solvothermal synthesis of ¦Á-PbO from lead dioxide and its electrochemical performance as a positive electrode material

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• 作者：Pengran Gao ; Yi Liu ; Xianfu Bu ; Meng Hu ; Yuan Dai ; Xiaorui Gao ; Lixu Lei
• 关键词：Lead monoxide ; Lead dioxide ; Methanol ; Solvothermal reaction ; Lead acid battery ; Positive material
• 刊名：Journal of Power Sources
• 出版年：2013
• 出版时间：15 November, 2013
• 年：2013
• 卷：242
• 期：Complete
• 页码：299-304
• 全文大小：2178 K

文摘

Lead acid batteries have been widely used and have dominated the global secondary battery market. It is very important to recycle the spent batteries efficiently to eliminate possible pollution and to ensure sustainable production. In this paper, we report our investigation on the solvothermal treatment of PbO₂, which is one of the model compounds for the positive active mixture, in methanol and the subsequent calcination of its product. The results show that the solvothermal treatment of PbO₂ in pure methanol at 140?¡ãC can produce a mixture of PbO and lead oxide carbonate, which can be calcined at a temperature below 500?¡ãC to produce ¦Á-PbO. The as-prepared PbO powders are rod-like particles of about 0.5 micrometer in diameter and several micrometers in length, which can achieve a high discharge capacity of 165?mAh?g^?1 at the discharge current density of 5?mA?g^?1, and more than 90?mAh?g^?1 at 200?mA?g^?1 with excellent cycle stability. This study demonstrates a new way for the reuse of lead dioxide in spent lead acid batteries to produce highly active PbO.