Complete doping in solid-state by silica-supported perchloric acid as dopant solid acid: Synthesis and characterization of the novel chiral composite of poly [(±)-2-(sec-butyl) aniline]
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- 作者：Abdolkarim Farrokhzadeh ; Ali Reza Modarresi-Alam ; modaresi@chem.usb.ac.ir" class="auth_mail" title="E-mail the corresponding author
- 关键词：Chiral conducting composite ; Poly [(± ; )-2-sec-butylaniline] ; Doping ; Silica-supported perchloric acid ; Solid-state
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：237
- 期：Complete
- 页码：258-268
- 全文大小：2457 K
文摘
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The solid-state synthesis of the novel chiral composites of poly[(±)-2-(sec-butyl)aniline] (PSBA) and silica-supported perchloric acid (SSPA).
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It takes 120 h for complete deprotonation of PSBA.HCl salt.
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Use of SSPA as dopant solid acid for the first time to attain the complete doping of PSBA.
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The coating of silica surface with PSBA.