Development of a support for a NiO catalyst for selective adsorption and post-adsorption catalytic steam gasification of thermally converted asphaltenes

详细信息    查看全文

• 作者：Azfar Hassan ; ^{azfar@ucalgary.ca} ; Francisco Lopez-Linares ; Nashaat N. Nassar ; Lante Carbognani-Arambarri ; Pedro Pereira-Almao
• 关键词：Quinoline-65 ; Asphaltenes ; Adsorption ; Catalytic steam gasification ; Meta kaolin ; Temperature programmed desorption
• 刊名：Catalysis Today
• 出版年：2013
• 出版时间：30 May, 2013
• 年：2013
• 卷：207
• 期：Complete
• 页码：112-118
• 全文大小：1167 K

文摘

Insight on the role of a new heterogeneous catalyst for catalytic steam gasification of adsorbed asphaltenes is reported. The catalyst was prepared by incorporating NiO nanoparticles into mesoporous-macroporous Ba-based meta kaolin intended both as catalyst support as well as adsorbent. Variations on the catalyst support were made in form of extrudates by adding a binder (Ba(CH₃COO)₂ and/or Ca(CH₃COO)₂) and sucrose as a porogenic substance, to kaolin and calcining in air typically at 650 ¡ãC. Effect of the binder type and content, sucrose content and calcination temperature upon adsorption was determined by performing adsorption study of Quinoline-65 (Q-65) using UV-Vis spectrophotometry. The surface basicity of catalyst support was measured by CO₂ temperature programmed desorption (TPD) experiments. Pore size distribution was determined by Nitrogen physisorption. The Q-65 uptake was correlated to the pore size distribution and the basicity of the adsorbents. The results suggest that solids having low surface basicity and with increased pore size distribution between 200 and 800 ? showed better adsorption. Further, incorporation of NiO nanoparticles into these catalyst supports not only enhanced the adsorption of asphaltenes, but also promoted the steam gasification of the adsorbed asphaltenes, leading to CO₂ and H₂ as major products.