Branched carbon-rich luminescent multinuclear platinum(II) and palladium(II) alkynyl complexes with phosphine ligands
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- 作者：Chi-Hang Tao ; Vivian Wing-Wah Yam
- 关键词：Luminescence ; Platinum(II) complexes ; Palladium(II) complexes ; Two-photon induced luminescence
- 刊名：Journal of Photochemistry and Photobiology, C: Photochemistry Reviews
- 出版年：2009
- 出版时间：September 2009
- 年：2009
- 卷：10
- 期：3
- 页码：130-140
- 全文大小：1080 K
文摘
In this review, the synthesis, electronic absorption and luminescent properties of a series of branched alkynylpalladium(II) and -platinum(II) phosphine complexes with different alkynyl backbones and some of their structurally related complexes in the literature will be discussed. With the growing research interest in the potential application of these complexes in the field of non-linear optics (NLO), the two-photon absorption (TPA) properties and the corresponding structure–property relationships of selected luminescent branched platinum(II) bis-alkynyl complexes will also be described.