DCDMH-promoted synthesis of thiophosphates by coupling of H-phosphonates with thiols

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• 作者：Xiaojing Bi ; Junchen Li ; Fanhua Meng ; Hongmei Wang ; Junhua Xiao ; ^{xiao.junhua@pku.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Thiophosphate ; DCDMH ; H-Phosphonate ; Thiol ; Phosphorylation
• 刊名：Tetrahedron
• 出版年：2016
• 出版时间：4 February 2016
• 年：2016
• 卷：72
• 期：5
• 页码：706-711
• 全文大小：729 K

文摘

DCDMH-mediated phosphorylation of versatile thiols with H-phosphonates for the preparation of synthetically and biologically important thiophosphates was demonstrated. Without metal catalysts and other additives, phosphorylation occurred to give the desired products with good to excellent yields within 10 min at ambient temperature in the air.