Molecular electrocatalysis of oxygen reduction by iron(II) phthalocyanine at the liquid/liquid interface
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- 作者：Yaofang Xuan ; Lisiqi Xie ; Xiao Huang ; Bin Su
- 关键词：Iron(II) phthalocyanine ; O2 reduction ; Liquid/liquid interface ; Catalysis ; Biphasic reaction
- 刊名：Journal of Electroanalytical Chemistry
- 出版年：2016
- 出版时间：1 April 2016
- 年：2016
- 卷：766
- 期：Complete
- 页码：37-43
- 全文大小：907 K
文摘
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ORR catalyzed by iron(II) phthalocyanine was studied at the liquid/liquid interface.
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The catalytic O2 reduction mainly produces H2O with only minority of H2O2 (less than 5%).
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The reaction possibly involves a hydroperoxo intermediate.