The compositional distinction between the lithospheric mantle samples is mirrored in the kamafugitic rocks of these two provinces, which suggests that the composition of these magmas was strongly influenced, or determined entirely, by the lithospheric mantle. Most of the kamafugitic rocks have 187Os/188Os higher than observed for peridotite, which suggests that the source of these magmas is a mixture of lithospheric peridotite of varying age, veined and/or interlayered with various olivine-poor components. The relatively limited range in Sr, Nd, and Hf isotopic composition of the mafic–alkalic magmas indicates that the olivine-poor component was added regionally, overprinting the incompatible-element characteristics of the lithospheric mantle beneath these provinces. The age of metasomatism in the lithospheric mantle of this area is poorly constrained, but the isotopic characteristics of the mafic–alkalic magmatism suggest that this event may have occurred during the mid- to late-Proterozoic assembly of the Brasília mobile belt.