The results of SEM and AFM directly showed that the surface of Cl2 etched samples were roughest with a Ge deficient damaged layer.
The XPS of Te 3d revealed the electrons were transferred from chalcogenide to halogen and the highest halogenation was observed on CF4 etching GST films.
The sidewall of HBr etching GST is nearly vertical compared with others.
HBr is promising gas for GST etching in the fabrication of high-density memory devices.