Novel approach to metal-induced oxidative phosphorylation of aromatic compounds
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- 作者：M.N. Khrizanforov ; khrizanforov@gmail.com" class="auth_mail" title="E-mail the corresponding author ; S.O. Strekalova ; K.V. Kholin ; V.V. Khrizanforova ; M.K. Kadirov ; T.V. Gryaznova ; Y.H. Budnikova
- 关键词：Phosphorylation ; Oxidation ; Electrosynthesis ; catalyst ; Metal ; Complex ; CH functionalization
- 刊名：Catalysis Today
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：279
- 期：part_P1
- 页码：133-141
- 全文大小：1416 K
文摘
- •
A single-step electrocatalytic method for aromatic C
H phosphonation is proposed.- •
The data of cyclic voltammetry and EPR for the system [MnIIbpy/NiIIbpy-(EtO)2P(O)H] are discussed.
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The electrosynthesis proceeds under mild conditions (room temperature) at potentials of 1.0 V [Ni-Mn-(EtO)2P(O)H] complex oxidation.