Syntheses, spectroscopic and thermal analyses of cyanide bridged heteronuclear polymeric complexes: [M(L)2Ni(CN)4]n (LN-methylethylenediamine or N-ethylethylenediamine; MNi(II), Cu(II), Zn(II) or Cd(II))
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- 作者：Dursun Karaağaç ; a ; ddkaraagac@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; Gü ; neş Sü ; heyla Kü ; rkç ; ü ; oğlub
- 关键词：Cyanide-bridged complexes ; Vibrational spectra ; DFT-B3LYP ; N-methylethylenediamine ; N-ethylethylenediamine ; Thermal analysis
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：5 February 2016
- 年：2016
- 卷：1105
- 期：Complete
- 页码：263-272
- 全文大小：1904 K
文摘
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New cyano-bridged heteronuclear polymeric complexes were synthesized.
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The complexes are characterized by FT-IR and Raman spectra.
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The Ni(II) ions are coordinated in square planar geometry.
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The M(II) ions are coordinated in distorted octahedral arrangement.