Flash cationic polymerization followed by bis-end-functionalization. A new approach to linear-dendritic hybrid polymers
详细信息 查看全文
- 作者：Yosuke Tani ; Masahiro Takumi ; Satori Moronaga ; Aiichiro Nagaki ; anagaki@sbchem.kyoto-u.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Jun-ichi Yoshida ; yoshida@sbchem.kyoto-u.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Flow microreactor ; Cationic polymerization ; Dendritic cation pool ; Functionalized linear-dendritic hybrid polymer ; Cross-coupling reaction
- 刊名：European Polymer Journal
- 出版年：2016
- 出版时间：July 2016
- 年：2016
- 卷：80
- 期：Complete
- 页码：227-233
- 全文大小：1206 K
文摘
- •
Cationic polymerization in a flow microreactor system gave multifunctional polymers.
- •
A dendritic cation having bromide moieties was used as the initiator.
- •
A silyl enol ether having bromide or alkynyl moieties was used as the terminators.
- •
Coupling reactions of both polymer ends gave linear-dendritic hybrid polymers.