Mechanical properties of nanostructured films with an ultralow volume fraction of hard phase

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• 作者：Marion Chenal^a ; ^b ; Cyril Vé ; chambre^c ; Jean-Marc Chenal^c ; Laurent Chazeau^c ; Vincent Humblot^d ; Laurent Bouteiller^a ; ^b ; Costantino Creton^e ; ^f ; ^g ; ^{costantino.creton@espci.fr} ; Jutta Rieger^a ; ^b ; ^{jutta.rieger@upmc.fr}
• 关键词：RAFT polymerization ; Film ; Nanostructure ; Core-shell latexes ; Mechanical properties
• 刊名：Polymer
• 出版年：2017
• 出版时间：27 January 2017
• 年：2017
• 卷：109
• 期：Complete
• 页码：187-196
• 全文大小：2185 K
• 卷排序：109

文摘

Nanostructured films containing a percolating network of PAA shells. High stiffness, extensibility and high fracture resistance. Tunable composition of block copolymer latex via the PISA approach. Tunable mechanical properties of the latex-derived films. Addition of cationic species in the serum modulates mechanical film properties.