Synthesis of three different galactose-based methacrylate monomers for the production of sugar-based polymers
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- 作者：Jessica S. Desporta ; 1 ; Daniele Mantionea ; 1 ; Mó ; nica Morenoa ; Haritz Sardó ; na ; Marí ; a J. Barandiarana ; David Mecerreyesa ; b ; daniele.mantione@ehu.es" class="auth_mail" title="E-mail the corresponding author ; david.mecerreyes@ehu.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Glycidyl methacrylate (GMA) ; Isopropylidene-D-galactopyranose ; AMC-2 catalyst ; Epoxide ring opening ; Free radical polymerization
- 刊名：Carbohydrate Research
- 出版年：2016
- 出版时间：2 September 2016
- 年：2016
- 卷：432
- 期：Complete
- 页码：50-54
- 全文大小：719 K
文摘
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Synthesis of three different methacrylate monomers based on galactopyranose.
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Glycidyl methacrylate (GMA) ring opening mechanisms is investigated.
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Regiospecific syntheses are described.
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Two new sugar-based polymers synthesize using free-radical polymerization.
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Characterization of the new polymers with TGA, DSC and GPC.