Crystal polymorphism of (μ4-O)-body centered adamantanoid Cu(II) complexes
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- 作者：V. Olijnyk ; wlodzimierz.olijnyk@uni.opole.pl" class="auth_mail" title="E-mail the corresponding author ; B. Zarychta
- 关键词：Cu(II) coordination sphere distortion ; O-body centered adamantanoid cage ; Packing and displacive polymorphism ; order&ndash ; disorder transformation
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：1106
- 期：Complete
- 页码：259-264
- 全文大小：676 K
文摘
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The polymorphic series of adamantanoid Cu(II) complexes with diallylsulfoxide is synthesized.
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Both packing and displacive polymorphism is observed.
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C3h → C4 distortion of Cu(II) coordination geometry underlies the static disorder.
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Order–disorder phase transitions are accompanied by multiple Jahn–Teller effects.