Aliphatic bromination with tetrabromomethane on immobilized copper complexes
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- 作者：Vladimir M. Zelikmana ; vomeze@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Irina G. Tarkhanovaa ; Alexey K. Buryakb
- 关键词：Metal complex catalysis ; Catalytic bromination ; Bromoalkanes ; Tetrabromomethane ; Polynuclear complexes
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2015
- 出版时间：October 2015
- 年：2015
- 卷：407
- 期：Complete
- 页码：60-66
- 全文大小：997 K
文摘
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We have designed novel catalysts for radical bromination of alkanes with CBr4.
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Addition of n-PrOH to the catalytic reaction leads to positive yield effect.
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The temperature dependence of the monobromodecanes yield has an extremal character.
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The monobromodecanes yield extremely depends on the alcohol concentration.