A new sandwich-type polyoxometalates containing mixed transition metals, [Cd2Zn2(H2O)2(P2W15O56)2]16∿/sup>: Syntheses, spectrochemical characterization and its
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- 作者：Farrokhzad Mohammadi Zonoz ; f.zonoz@hsu.ac.ir" class="auth_mail" title="E-mail the corresponding author ; fzmohamadi@yahoo.com" class="auth_mail" title="E-mail the corresponding author ; Fatemeh Aliabadi
- 关键词：Polyoxometalate ; Sandwich complexes ; Cadmium ; Electrochemistry
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 April 2016
- 年：2016
- 卷：444
- 期：Complete
- 页码：87-94
- 全文大小：1685 K
文摘
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This compound is a new polyoxometalates containing mixed transition metals.
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The cadmium ions are located in external position at M4O16 metal centers.
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This mixed-metal polyoxometalate can catalyze electrochemical reduction of NO2−.
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By reducing the number of cadmium ions, catalytic efficiency increases.