Ionic liquids-functionalized porphyrins as bifunctional catalysts for cycloaddition of carbon dioxide to epoxides
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- 作者：Xu Jianga ; Faliang Goua ; Xiying Fua ; Huanwang Jinga ; b ; hwjing@lzu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Carbon dioxide ; Epoxides ; Cyclic carbonates ; Ionic liquids-functionalized porphyrin ; Bifunctional catalysts
- 刊名：Journal of CO2 Utilization
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：16
- 期：Complete
- 页码：264-271
- 全文大小：1404 K
文摘
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New and efficient ionic liquids-functionalized metalloporphyrin catalysts were designed and synthesized for the PO/CO2 cycloaddition.
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Catalysts demonstrated excellent reactivity and selectively.
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The catalytic performance is strongly dependent on both halogen anionic species and cationic structural nature.