Tailoring polyethylenes through constraining geometry of nickel complex: Synthesis, characterization and ethylene polymerization of 8-(2-benzhydrylnaphthylimino)-5,6,7-trihydroquinolylnickel halides
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- 作者：Erlin Yuea ; b ; Yanning Zengb ; Wenjuan Zhangb ; Fang Huangb ; Xiao-Ping Caoa ; caoxplzu@163.com" class="auth_mail" title="E-mail the corresponding author ; Tongling Liangb ; Wen-Hua Sunb ; c ; whsun@iccas.ac.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Nickel complex ; Ethylene polymerization ; Polyethylene wax
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：442
- 期：Complete
- 页码：178-186
- 全文大小：1356 K
文摘
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New 8-(2-benzhydrylnaphthylimino)-5,6,7-trihydroquinolylnickel halides.
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All nickel precatalysts exhibited high activities toward ethylene polymerization.
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Polyethylenes obtained contain tail peaks in the high molecular weight portion.
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Polyethylenes with low molecular weights.
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Polyethylenes potentially useful as lubricants and pour-point depressants.