A novel processing method namely fast evaporation mixing to prepare fluoroelastomer/montmorillonite composites

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• 作者：Wei Gao ; Jianhua Guo ; ^{psjhguo@126.com}
• 关键词：Fluoroelastomer ; Montmorillonite ; Nanocomposite ; Fast evaporation mixing ; Melting mixing
• 刊名：Composites Science and Technology
• 出版年：2017
• 出版时间：8 February 2017
• 年：2017
• 卷：139
• 期：Complete
• 页码：26-35
• 全文大小：3792 K
• 卷排序：139

文摘

Fluoroelastomer (FKM)/montmorillonite (MMT) nanocomposites were prepared by fast evaporation mixing and melting mixing, respectively. The mechanical properties and curing behaviors of the nanocomposites prepared by the two methods were compared. The nanocomposites were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), rubber processing analysis (RPA), thermal gravity analysis (TGA) and dynamic mechanical analysis (DMA). The results indicate that the nanocomposites that were prepared by fast evaporation mixing show better mechanical properties than those prepared by melting mixing according to the increase of the MMT contents from 0.5 to 2.5 phr. When the MMT content was 2.5 phr, exfoliated MMT platelets were found to disperse uniformly in the FKM matrix and the nanocomposites possessed a higher tanδmax and weaker Payne effect. By contrast, some aggregated MMT appeared in the matrix by melting mixing, which led to a lower tanδmax and stronger Payne effect. Therefore, fast evaporation mixing is an eco-friendly and simple processing technology that can be used to realize a good dispersion of nano-fillers in a rubber matrix.