The PSCs properties of BPz derivatives based donor polymers can be affected by the different side chain substitutions.
The HOMO of PBDT-BPzC with 2,7-alkyl substituted is significantly lower than PBDT-OBPz with 11,12-alkoxy substituted.
PBDT-BPzC significantly enhances the Voc and PCE, compared with PBDT-OBPz.