Sn0.97Ag0.03Se crystal was grown by a novel horizontal Bridgman method. B2O3 encapsulant was used to prevent Se volatilization during crystal growth. Sn0.97Ag0.03Se single crystal about 25×20×15 mm3 in dimensions was obtained. ZT=0.95 was obtained under 793 K corresponding to Pnma-Cmcm phase transition temperature.