Morphology of particles was characterized using atomic force microscopy (AFM). AFM micrographs illustrate the uniform size distribution of silica microspheres in colloidal crystal. With the variation of molarities of reactants, sizes of particles are controlled. Photonic band gap calculations are carried out to show pseudo-photonic band gap of silica opals.
Optical characterization proves photonic character of colloidal crystals. It is noticed that forbidden photonic band gap depends on size of spheres forming colloidal crystal. Materials with controllable interesting photonic property are realized by easy and non expensive route and modifying position of stop-band allows to improved engineering of colloidal photonic crystals.