Degradation of tris(2-chloroethyl) phosphate by ultraviolet-persulfate: Kinetics, pathway and intermediate impact on proteome of Escherichia coli
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- 作者：Hua-se Oua ; Juan Liua ; Jin-shao Yea ; b ; jinshaoye@lbl.gov" class="auth_mail" title="E-mail the corresponding author ; folaye@126.com" class="auth_mail" title="E-mail the corresponding author ; Lin-lin Wanga ; b ; Nai-yun Gaoc ; Jing Keb
- 关键词：Organophosphorus flame retardants ; Ultraviolet ; Persulfate ; Advanced oxidation process ; Proteomics
- 刊名：Chemical Engineering Journal
- 出版年：2017
- 出版时间：15 January 2017
- 年：2017
- 卷：308
- 期：Complete
- 页码：386-395
- 全文大小：1738 K
文摘
- •
254 nm ultraviolet/persulfate induces rapid degradation of TCEP.
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Three intermediates are generated by selective electron-transfer of
SO4−.- •
The impact of TCEP and intermediates on E. coli protein expression is compared.
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Degrading TCEP induces less stress on E. coli than intact CIP.
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The
SO4−-based incomplete degradation reduces the toxicity of TCEP.