Ruthenium carbonyl complex of a redox non-innocent ONS donor azophenol ligand: Electrochemistry, photophysical property, electronic structure and catalytic activity towards oxidation of alcohols

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• 作者：Puspendu Roy ; Apurba Sau Mondal ; Ajoy Kumar Pramanik ; Tapan Kumar Mondal ; ^{tkmondal@chemistry.jdvu.ac.in}
• 关键词：Ruthenium carbonyl complex ; ONS donor azophenol ligand ; X-ray structure ; Electronic structure ; Electrochemistry ; Catalytic activity
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 January 2017
• 年：2017
• 卷：828
• 期：Complete
• 页码：1-9
• 全文大小：1341 K
• 卷排序：828

文摘

A ruthenium carbonyl complex of a redox non-innocent thioether-containing azo-phenol ligand has been synthesized and characterized. Cyclic voltammetric study has been used to interpret the redox properties. Absorption and emission properties have been studied. Catalytic oxidation of alcohols has been studied in presence of NMO. DFT calculations have been used to interpret the electronic structure.