Catalytic homogeneous oxidation of monoterpenes and cyclooctene with hydrogen peroxide in the presence of sandwich-type tungstophosphates [M4(H2O)2(PW9O34)2]n−, M = CoII, MnII and FeIII
文摘
Sandwich-type B‐α‐[M4(H2O)2(PW9O34)2]n− (M = CoII, MnII, FeIII) polyoxometalates. Oxidation of limonene, geraniol, linalool, carveol, and cyclooctene. Oxidation with 30% (w/w) aqueous hydrogen peroxide, in acetonitrile. The main/unique oxidation pathway for terpenoids and cyclooctene is epoxidation.