Coke formation of model compounds relevant to pyrolysis bio-oil over ZSM-5
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- 作者：Shoucheng Dua ; David P. Gamliela ; Marcus V. Giottob ; Julia A. Vallaa ; George M. Bollasa ; george.bollas@uconn.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Heterogeneous catalysis ; Biomass ; Catalytic pyrolysis ; Coke characterization ; Coke formation chemistry
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：5 March 2016
- 年：2016
- 卷：513
- 期：Complete
- 页码：67-81
- 全文大小：2754 K
文摘
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Toluene, propylene, tolualdehyde and furan were catalytically pyrolyzed over ZSM-5.
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Coke forms via oligomerization and polymerization of aromatics and olefins.
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Catalytic reactions produce coke with higher crystallinity and higher H/C ratio.
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Chemical structures for coke are proposed, satisfying 13C NMR and elemental analysis.