Silicon isotope fractionation in silicate minerals: Insights from first-principles models of phyllosilicates, albite and pyrope

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• 作者：Merlin Mé ; heut^a ; ^{merlin.meheut@get.obs-mip.fr" class="auth_mail} ; Edwin A. Schauble^b
• 刊名：Geochimica et Cosmochimica Acta
• 出版年：1 June 2014
• 年：2014
• 卷：134
• 期：Complete
• 页码：137-154
• 全文大小：2074 K

文摘

Isotopic fractionation factors for oxygen and silicon in phyllosilicates (pyrophyllite, talc), albite and pyrope have been calculated using first-principles methods based on density functional theory. Based on exhaustive analysis of numerical convergence, we also update our previous calculations on enstatite and forsterite silicon fractionation properties. Calculated oxygen isotope fractionations agree well with existing estimates for talc and albite. In the case of silicon, qualitative agreement is found with natural data. For phyllosilicates (kaolinite, lizardite, pyrophyllite, talc), Si isotope fractionation properties appear to be correlated with stoichiometry:

where Si^eq. =#Si, ${\mathrm{Al}}^{\mathrm{eq}.}=\frac{3}{4}\#\mathrm{Al}$ and ${\mathrm{Mg}}^{\mathrm{eq}.}=\frac{1}{2}\#\mathrm{Mg}$ (cation equivalents) are the charge-weighed stoichiometric coefficients of each cation, normalized to the charge of the silicon atom, and a_X(T)$a_{\mathrm{X}}(T)$ are proportionality coefficients depending on temperature. It is suggested that the effect of cation X on Si isotope fractionation (i.e. a_X(T)$a_{\mathrm{X}}(T)$) will increase with decreasing electronegativity of X. Si isotope fractionation is further correlated with Si–O distances, suggesting a crystal chemical explanation for relation (1) in terms of electron donation effects. This relationship appears valid for quartz, pyrope and enstatite $(R^2=0.99\text{,}n=7)$, but forsterite is strongly anomalous (error of 0.7‰ at 600 °C). These models indicate that attention should be given to chemical compositions in Si isotope studies. Relation (1) would explain the enrichment in heavy silicon isotopes accompanying magmatic differentiation.