A novel organometallic macrocycle based on half-sandwich ruthenium motif
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- 作者：Xiu-Xiu Li ; Qing-Ya He ; Fanghui Wu ; Guozan Yuan ; Wei-Bin Yu ; yuweibin@ahut.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Half-sandwich ruthenium ; Macrocycle ; Cyclic voltammetry ; Characterization ; Electronic properties ; Organic linker
- 刊名：Inorganica Chimica Acta
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：454
- 期：Complete
- 页码：54-57
- 全文大小：916 K
文摘
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A newly metallamacrocycle was formed under mild conditions based on half-sandwich ruthenium fragments.
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The novel macrocycle has good electronic property for catalyzing water oxidation under alkaline condition.
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The weak interaction of H-bonding was favorable to construct channel architecture.