Accelerated desupersaturation of reverse osmosis concentrate by chemically-enhanced seeded precipitation

详细信息    查看全文

• 作者：Anditya Rahardianto ; Brian C. McCool ; Yoram Cohen
• 关键词：High recovery RO desalting ; Desalination concentrate treatment ; Antiscalant scavenging/deactivation ; Calcium sulfate precipitation kinetics ; Precipitation softening ; Membrane mineral scaling
• 刊名：Desalination
• 出版年：2010
• 出版时间：31 December 2010
• 年：2010
• 卷：264
• 期：3
• 页码：256-267
• 全文大小：1926 K

文摘

A two-step chemically-enhanced seeded precipitation (CESP) process was demonstrated for accelerated desupersaturation of antiscalant-containing, gypsum-supersaturated model solutions, which mimicked reverse osmosis (RO) concentrate from RO desalting of agricultural drainage water of high mineral scaling propensity. In the CESP process, CaCO₃ precipitation is first induced via lime dosing for antiscalant scavenging, followed by subsequent CaSO₄ precipitation via gypsum seeding for concentrate desupersaturation. It was demonstrated that lime-precipitated CaCO₃ particles were able to scavenge generic and commercial polycarboxylic-acid antiscalants, thereby facilitating subsequent CaSO₄ precipitation to progress with minimal retardation. The study demonstrated via a series of batch CESP cycles that gypsum particle recycling can sustain CaSO₄ precipitation, suggesting that a continuous CESP process could be feasible. Process analysis suggests that CESP can be significantly less chemical-intensive than conventional precipitation softening and, with its integration as an intermediate RO concentrate demineralization process, can enable desalination water recovery enhancement via secondary RO desalting. For the present case of gypsum-saturated RO feed water, enhancement of overall water recovery from 63 % up to 87 % or higher appears to be feasible. The study suggests that there is merit for developing a continuous CESP process for high recovery RO desalting of brackish water of high gypsum scaling propensity.