Metal nitrosyl chemistry: Interesting oxidation and nitrosylation of a metal-bound ligand framework in a diamido-bis(phosphine) ruthenium(II) complex
详细信息 查看全文
- 作者：Daniel N. Huhb ; Eric T. Czerc ; Kyle E. Cordovad ; Wesley I. Chowe ; Curtis E. Moorea ; Arnold L. Rheingolda ; Christopher J.A. Daleye ; cjdaley@sandiego.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ruthenium-diamido and diimino-bis(phosphine) complexes ; X-ray crystal structures ; Nitric oxide ; Metal-activated nitrosylation ; Dioxime
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 August 2016
- 年：2016
- 卷：450
- 期：Complete
- 页码：236-242
- 全文大小：1103 K
文摘
- •
A Trost diamidato-bis(phosphine)-based ligand Ru(II)Cl2 compound was prepared.
- •
A ligand-oxidized-nitrosylated Ru(II)Cl2 complex was made on reaction with NO+.
- •
Solid state (X-ray) and solution (NMR) structures of the complexes are reported.