Stability of low-temperature Li7La3Zr2O12 cubic phase: The role of temperature and atmosphere
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- 作者：Irene Quinzenia ; Doretta Capsonia ; Vittorio Berbennia ; Piercarlo Mustarellia ; Michela Sturinib ; Marcella Binia ; bini@unipv.it" class="auth_mail" title="E-mail the corresponding author
- 关键词：Li7La3Zr2O12 ; XRPD ; High temperature X-ray powder diffraction ; Rietveld refinement ; TGA-DSC
- 刊名：Materials Chemistry & Physics
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：185
- 期：Complete
- 页码：55-64
- 全文大小：684 K
文摘
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Li7La3Zr2O12 is a promising electrolyte for rechargeable all solid state batteries.
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The stability of low temperature cubic phase of garnet in argon and air was determined.
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The garnet stoichiometry was maintained in argon while in air lithium loss occurred.
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The influence of CO2 adsorption on the structural modifications of garnet was proved.