Synthesis, pyrolytic and bioassay studies of complexes Ni(II), Cu(II) and Zn(II) bromides with a chelating ligand of N,N donor sites

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• 作者：Saeed-Ur-Rehman ; Sadia Rehman ; Muhammad Ikram ; Farhat Ullah
• 关键词：Aminobenzohydrazine ; Coordination compounds ; Thermal ; Bioassay
• 刊名：Journal of Saudi Chemical Society
• 出版年：2013
• 出版时间：October, 2013
• 年：2013
• 卷：17
• 期：4
• 页码：353-359
• 全文大小：755 K

文摘

Coordination complexes of modified hydrazine are prepared with Ni(II), Cu(II), and Zn(II) metal ions. The ligand is synthesized by removing the methoxy moiety of methyl anthranilate with nitrogen of hydrazine hydrate, creating new coordination site. The coordination complexes are synthesized by reacting the ABH ligand with dehydrated M(II) [Cu²⁺, Zn²⁺ and Ni²⁺] bromide in an inert environment. The structures of the coordination complexes are elucidated basing on the physical measurements including elemental analysis, NMR, IR, UV-Vis spectra, magnetic and conductance measurements. These results reflect the M(ABH)Br₂ composition of the corresponding complexes. Thermal studies show the Irving William trend for the stability of complexes. Antibacterial activities and antifungal studies are also carried out in order to investigate the biological activity upon complexation.